大井研究室 Publications

原著論文 : Original Papers

68.

Diastereo- and enantioselective phase-transfer alkylation of 3-substituted oxindoles with racemic secondary alkyl halides

Kohsuke Ohmatsu, Yukino Furukawa, Mari Kiyokawa and Takashi Ooi

Chem. Commun. 2017, XX, xxxx-xxxx

DOI: 10.1039/C7CC07122A

67.

Photoredox Ketone Catalysis for Direct C-H Imidation and Acyloxylation of Arenes

Chandra Bhushan Tripathi, Tsuyoshi Ohtani, Michael T. Corbett and Takashi Ooi

Chem. Sci. 2017, 8, 5622-5627

DOI: 10.1039/C7SC01700F

66.

Determination of the absolute configuration of compounds bearing chiral quaternary carbon centers using the crystalline sponge method

Shiho Sairenji, Takashi Kikuchi, Mohamed Ahmed Abozeid, Shinobu Takizawa, Hiroaki Sasai, Yuichiro Ando, Kohsuke Ohmatsu, Takashi Ooi and Makoto Fujita

Chem. Sci. 2017, 8, 5132-5136

DOI: 10.1039/c7sc01524k

65.

N-Sulfonyl α-Imino Ester-Derived Chiral Oxaziridines: Catalytic Asymmetric Synthesis and Application as a Modular Chiral Organic Oxidant

Naoya Tanaka, Ryosuke Tsutsumi, Daisuke Uraguchi,Takashi Ooi

Chem. Commun. 2017, 53, 6999-7002

DOI: 10.1039/C7CC02502E

Selected as a "Cover Picture"

64.

Unique Site-selectivity Control in Asymmetric Michael Addition of Azlactone to Alkenyl Dienyl Ketones Enabled by P-Spiro Chiral Iminophosphorane Catalysis

Ken Yoshioka, Kohei Yamada, Daisuke Uraguchi,Takashi Ooi

Chem. Commun. 2017, 53, 5495-5498

DOI: 10.1039/C7CC01715D

Themed Issue “Site-selective molecular transformations”

Selected as a "Cover Picture"

63.

Acridinium Betaine as a Single-Electron-Transfer Catalyst: Design and Application to Dimerization of Oxindoles

Daisuke Uraguchi, Masahiro Torii, Takashi Ooi

ACS Catal. 2017, 7, 2765-2769

DOI: 10.1021/acscatal.7b00265

62.

Complete diastereodivergence in asymmetric 1,6-addition reactions enabled by minimal modification of a chiral catalyst

Daisuke Uraguchi, Ken Yoshioka, Takashi Ooi

Nature Communications 2017, 8, 14793

DOI: 10.1038/ncomms14793

Highlighted in EurekAlert!

Highlighted in Chem Europe

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Highlighted in Phys.org

プレスリリース (名古屋大学HP)

中日新聞(2017年4月4日)掲載

61.

[5.5]-P-Spirocyclic Chiral Triaminoiminophosphorane-Catalyzed Asymmetric Hydrophosphonylation of Aldehydes and Ynones

Daisuke Uraguchi, Takaki Ito, Yuto Kimura, Yumiko Nobori, Makoto Sato, Takashi Ooi

Bull. Chem. Soc. Jpn. 2017, 90, 546-555

DOI: 10.1246/bcsj.20170040

Highlighted as a "Selected Papers(SP)"

60.

In Situ Electrophilic Activation of Hydrogen Peroxide for Catalytic Asymmetric α-Hydroxylation of 3-Substituted Oxindoles

Kohsuke Ohmatsu, Yuichiro Ando, Takashi Ooi

Synlett 2017, 28, 1291-1294

DOI: 10.1055/s-0036-1558958

SYNLETT Cluster: Asymmetric Brønsted Base Catalysis

Selected as a " News article"

Selected as a " Front Cover"

59.

Stereoselective Aza-Henry Reaction of 3-Nitro-Dihydro-2(1H)-Quinolones with N-BOC-Aldimines under the Catalysis of Chiral Ammonium Betaines

Daisuke Uraguchi, Masahiro Torii, Kohsuke Kato, Takashi Ooi

Heterocycles 2017, 94, 441-447

DOI: 10.3987/COM-16-13642

58.

A Modular Strategy for the Direct Catalytic Asymmetric α-Amination of Carbonyl Compounds

Kohsuke Ohmatsu, Yuichiro Ando, Tsubasa Nakashima, Takashi Ooi

Chem 2016, 1, 802-810

DOI: 10.1016/j.chempr.2016.10.012

Highlighted in Chem-Station (化学者のつぶやき)

Highlighted in Phys.Org

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プレスリリース (名古屋大学HP)

中日新聞・日経産業新聞・日刊工業新聞 (2016年11月11日), 科学新聞(2016年11月25日)掲載

57.

Origin of High Regio-, Diastereo-, and Enantioselectivities in 1,6-Addition of Azlactones to Dienyl N-Acylpyrroles: A Computational Study

Yamanaka, Masahiro; Sakata, Ken; Yoshioka, Ken; Uraguchi, Daisuke; Ooi, Takashi

J. Org. Chem. 2017, 82, 541-548

DOI: 10.1021/acs.joc.6b02572

56.

Chiral Ammonium Betaine-Catalyzed Asymmetric Mannich-Type Reaction of Oxindoles

Masahiro Torii, Kohsuke Kato, Daisuke Uraguchi, and Takashi Ooi

Beilstein J. Org. Chem. 2016, 12, 2099-2103

DOI: 10.3762/bjoc.12.199

Thematic Series “Strategies in Asymmetric Catalysis”

55.

Independence from the Sequence of Single-Electron Transfer of Photoredox Process in Redox-Neutral Asymmetric Bond-Forming Reaction

Tomohito Kizu, Daisuke Uraguchi, and Takashi Ooi

J. Org. Chem. 2016, 81, 6953-6958

DOI: 10.1021/acs.joc.6b00445

Special Issue on Photocatalysis

54.

Multiple Absolute Stereocontrol in Pd-Catalyzed [3+2] Cycloaddition of Oxazolidinones and Trisubstituted Alkenes Using Chiral Ammonium-Phosphine Hybrid Ligands

Naomichi Imagawa, Yuya Nagato, Kohsuke Ohmatsu, and Takashi Ooi

Bull. Chem. Soc. Jpn. 2016, 89, 649-656

DOI: 10.1246/bcsj.20160053

Selected as a "selected as BCSJ Award Article and Cover Picture"

53.

Anion-Stoichiometry-Dependent Selectivity Enhancement in Ion-Paired Chiral Ligand-Palladium Complex Catalyzed Enantioselective Allylic Alkylation

Kohsuke Ohmatsu, Yoshiyuki Hara, Yuya Kusano, Takashi Ooi

Synlett 2016, 27, 1047-1050

DOI: 10.1055/s-0035-1561403

SYNLETT Cluster: Non-Covalent Interactions in Asymmetric Catalysis

52.

Palladium-Catalyzed Branch-Selective Decarboxylative Allylation Using Ion-Paired Ligands

Yoshiyuki Hara, Yuya Kusano, Kohsuke Ohmatsu, and Takashi Ooi

Chem. Lett. 2016, 45, 552-554

DOI: 10.1246/cl.160158

Selected as a "Editor's Choice"

51.

Synergistic Catalysis of Ionic Brønsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines

Daisuke Uraguchi, Natsuko Kinoshita, Tomohito Kizu, and Takashi Ooi

J. Am. Chem. Soc. 2015, 137, 13768-13771

DOI: 10.1021/jacs.5b09329

Highlighted in Synfacts 2016, 12, 0196.

Highlighted in Organic Chemistry Portal.

50.

Enantioselective Reductive Multicomponent Coupling Reactions between Isatins and Aldehydes

Matthew A. Horwitz, Naoya Tanaka, Takuya Yokosaka, Daisuke Uraguchi, Jeffrey S. Johnson, and Takashi Ooi

Chem. Sci. 2015, 6, 6086-6090

DOI: 10.1039/C5SC02170G

Selected as a "Outside Back Cover"

49.

Catalytic Asymmetric Cyanation of Alkylideneindolenines Generated from Sulfonylalkylindoles

Kohsuke Ohmatsu, Yukino Furukawa, Daigo Nakaguro, and Takashi Ooi

Chem. Lett. 2015, 44, 1350-1352

DOI: 10.1246/cl.150581

48.

Highly E- and Enantioselective Michael Addition to Electron-deficient Internal Alkynes under the Catalysis of Chiral Iminophosphorane

Daisuke Uraguchi, Kohei Yamada, Takashi Ooi

Angew. Chem. Int. Ed. 2015, 54, 9954-9957

DOI: 10.1002/anie.201503928

47.

Vinylogy in Nitronates: Utilization of α-Aryl Conjugated Nitroolefins as a Nucleophile for Highly Stereoselective Aza-Henry Reaction

Keigo Oyaizu, Daisuke Uraguchi, Takashi Ooi

Chem. Commun. 2015, 51, 4437-4439

DOI: 10.1039/C4CC10261D

46.

Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of 5-Vinyloxazolidinones with Imines Using Chiral Ammonium-Phosphine Hybrid Ligand

Kohsuke Ohmatsu, Shinya Kawai, Naomichi Imagawa, Takashi Ooi

ACS Catal. 2014, 4, 4304-4306

DOI: 10.1021/cs501369z

Selected as a "Cover Picture"

45.

Chiral Ammonium Betaine-Catalyzed Highly Stereoselective Aza-Henry Reaction of α-Aryl Nitromethanes with Aromatic N-Boc Imines

Daisuke Uraguchi, Keigo Oyaizu, Haruhiro Noguchi, Takashi Ooi

Chem. Asian J. 2014, 10, 334-337

DOI: 10.1002/asia.201402943

Selected as a "Inside Cover"

44.

Enantioselective Protonation of α-Hetero Carboxylic Acid-Derived Ketene Disilyl Acetals under Chiral Ionic Brønsted Acid Catalysis

Daisuke Uraguchi, Tomohito Kizu, Yuki Ohira, Takashi Ooi

Chem. Commun. 2014, 50,13489-13491

DOI: 10.1039/C4CC06081D

43.

In-Situ Generation of Ion-Paired Chiral Ligands: Rapid Identification of Optimal Ligand for Palladium-Catalyzed Asymmetric Allylation

Kohsuke Ohmatsu, Yoshiyuki Hara, Takashi Ooi

Chem. Sci. 2014, 5, 3645-3650

DOI: 10.1039/C4SC01032A

42.

Enantioselective formal α-allylation of nitroalkanes through a chiral iminophosphorane-catalyzed Michael reaction-Julia-Kocienski olefination sequence

Daisuke Uraguchi, Shinji Nakamura, Hitoshi Sasaki, Yuki Konakade, Takashi Ooi

Chem. Commun. 2014, 50, 3491-3493

DOI: 10.1039/C3CC49477B

41.

Practical Preparation of Chiral N-Sulfonyl Oxaziridines by Catalytic Asymmetric Payne Oxidation

Ryosuke Tsutsumi, Seonwoo Kim, Daisuke Uraguchi, Takashi Ooi

Synthesis (PSP article) 2014, 46, 871-878

DOI: 10.1055/s-0033-1340818

Highlighted in organic chemistry portal

40.

Ligand-controlled E/Z selectivity and enantioselectivity in palladium-catalyzed allylation of benzofuranones with 1,2-disubstituted allylic carbonates

Kohsuke Ohmatsu, Mitsunori Ito , Takashi Ooi

Chem. Commun. 2014, 50, 4554-4557

DOI: 10.1039/C3CC49338E

Highlighted in Synfacts 2014, 706.

Selected as a "Outside Back Cover"

39.

Asymmetric Alkylation of α-Cyanosulfones Catalyzed by Chiral 1,2,3-Triazolium Salts

Kohsuke Ohmatsu, Yusuke Hakamata, Ayano Goto, Takashi Ooi

Heterocycles 2014, 88, 1661-1666

DOI: 10.3987/COM-13-S(S)121

38.

Catalytic asymmetric Payne oxidation under the catalysis of P-spiro chiral triaminoiminophosphorane: Application to the synthesis of N-sulfonyl oxaziridines

Daisuke Uraguchi, Ryosuke Tsutsumi, Takashi Ooi

Tetrahedron 2014, 70, 1691-1701

DOI: 10.1016/j.tet.2013.12.086

Highlighted as a cover figure

37.

Asymmetric Substitution at the Tetrasubstituted Chiral Carbon: Catalytic Ring-Opening Alkylation of Racemic 2,2-Disubstituted Aziridines with 3-Substituted Oxindoles

Kohsuke Ohmatsu, Yuichiro Ando , Takashi Ooi

J. Am. Chem. Soc. 2013, 135, 18706-18709

DOI: 10.1021/ja411647x

36.

Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocenters

Kohsuke Ohmatsu, Naomichi Imagawa, Takashi Ooi

Nature Chem. 2014, 6, 47-51

DOI: 10.1038/nchem.1796

Highlighted in Synform 2014, A81-84. http://dx.doi.org/10.1055/s-0033-1339014 (Synstory)

Highlighted in Synfacts 2014, 354. http://dx.doi.org/10.1055/s-0033-1341001

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プレスリリース (名古屋大学HP)

中日新聞・日経産業新聞 (2013年11月25日)掲載

CBCテレビ(2013年11月25日)

35.

Carbene Transfer from Triazolylidene Gold Complexes as a Potent Strategy for Inducing High Catalytic Activity

Daniel Canseco-Gonzalez, Ana Petronilho, Helge Mueller-Bunz, Kohsuke Ohmatsu, Takashi Ooi, Martin Albrecht

J. Am. Chem. Soc. 2013, 135, 13193-13203

DOI: 10.1021/ja406999p

34.

Catalytic Asymmetric Oxidation of N-Sulfonyl Imines with Hydrogen Peroxide−Trichloroacetonitrile System

Daisuke Uraguchi, Ryosuke Tsutsumi, and Takashi Ooi

J. Am. Chem. Soc. 2013, 135, 8161-8164

DOI: 10.1021/ja403491j

Highlighted in Synfacts 2013, 1005.

33.

Exploiting the Modularity of Ion-Paired Chiral Ligands for Palladium-Catalyzed Enantioselective Allylation of Benzofuran-2(3H)-ones

Kohsuke Ohmatsu, Mitsunori Ito, Tomoatsu Kunieda, and Takashi Ooi

J. Am. Chem. Soc. 2013, 135, 590−593

DOI: 10.1021/ja312125a

Highlighted in Synfacts 2013, 407.

32.

Highly Stereoselective Michael Addition of Azlactones to Electron-Deficient Triple Bonds under P-Spiro Chiral Iminophosphorane Catalysis: Importance of Protonation Pathway

Uraguchi, Daisuke; Ueki, Yusuke; Sugiyama, Atsushi; Ooi, Takashi

Chem. Sci. 2013, 4, 1308-1311

DOI: 10.1039/C2SC22027J

31.

Highly Regio-, Diastereo-, and Enantioselective 1,6- and 1,8-Additions of Azlactones to Di- and Trienyl N-Acylpyrroles

Uraguchi, Daisuke; Yoshioka, Ken; Ueki, Yusuke; Ooi, Takashi

J. Am. Chem. Soc. 2012, 134, 19370-19373.

DOI: 10.1021/ja311719f

Highlighted in JACS Spotlights

Highlighted in Synfacts 2013, 217. http://dx.doi.org/10.1055/s-0032-1318035

30.

Chiral Ionic Brønsted Acid-Achiral Brønsted Base Synergistic Catalysis for Asymmetric Sulfa-Michael Addition to Nitroolefins

Uraguchi, Daisuke; Kinoshita, Natsuko; Nakashima, Daisuke; Ooi, Takashi

Chem. Sci. 2012, 3, 3161-3164.

DOI: 10.1039/C2SC20698F

Selected as a "Outside Back Cover"

29.

Catalytic Asymmetric Ring Openings of Meso and Terminal Aziridines with Halides Mediated by Chiral 1,2,3-Triazolium Silicates

Ohmatsu, Kohsuke; Hamajima, Yuta; Ooi, Takashi

J. Am. Chem. Soc. 2012, 134, 8794-8797.

DOI: 10.1021/ja3028668

Highlighted in Synfacts 2012, 892. http://dx.doi.org/10.1055/s-0032-1316631

Highlighted in Synfacts 2012, 911. http://dx.doi.org/10.1055/s-0032-1316697

28.

Catalytic Asymmetric Mannich-Type Reactions of α-Cyano α-Sulfonyl Carbanions

Ohmatsu, Kohsuke; Goto, Ayano; Ooi, Takashi

Chem. Commun. 2012, 48, 7913-7915.

DOI: 10.1039/C2CC32398B

Selected as a "Cover Picture"

27.

Nitroolefins as a Nucleophilic Component for Highly Stereoselective Aza-Henry Reaction under the Catalysis of Chiral Ammonium Betaines

Uraguchi, Daisuke; Oyaizu, Keigo; Ooi, Takashi

Chem. Eur. J. 2012, 18, 8306-8309.

DOI: 10.1002/chem.201201259

26.

Ionic Nucleophilic Catalysis of Chiral Ammonium Betaines for Highly Stereoselective Aldol Reaction from Oxindole-Derived Vinylic Carbonates

Uraguchi, Daisuke; Koshimoto, Kyohei; Ooi, Takashi

J. Am. Chem. Soc. 2012, 134, 6972-6975.

DOI: 10.1021/ja3022939

Highlighted in Synfacts 2012, 670. http://dx.doi.org/10.1055/s-0031-1291036

25.

Ion-paired chiral ligands for asymmetric palladium catalysis

Ohmatsu, Kohsuke; Ito, Mitsunori; Kunieda, Tomoatsu; Ooi, Takashi

Nat. Chem. 2012, 4, 473-477.

DOI:10.1038/nchem.1311

Highlighted in Nature Chemistry (News and Views)

Highlighted in Synfacts 2012, 876. http://dx.doi.org/10.1055/s-0032-1316660

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プレスリリース (名古屋大学HP)

中日新聞 (2012年4月2日朝刊)掲載

NHKおはよう東海(2012年4月2日)

24.

Base-Catalyzed Direct Aldolization of α-Alkyl-α-Hydroxy Trialkyl Phosphonoacetates

Corbett, Michael; Uraguchi, Daisuke; Ooi, Takashi; Johnson, Jeffrey

Angew. Chem. Int. Ed. 2012, 51, 4685-4689.

DOI: 10.1002/anie.201200559

23.

Highly Stereoselective Catalytic Conjugate Addition of Acyl Anion Equivalent to Nitroolefins

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

Chem. Sci. 2012, 3, 842-845.

DOI: 10.1039/C1SC00678A

22.

Enantioselective Aza-Michael Addition to Conjugated Nitroenynes Catalyzed by Chiral Arylaminophosphonium Barfates

Uraguchi, Daisuke; Kinoshita, Natsuko; Kizu, Tomohito; Ooi, Takashi

Synlett. 2011, 1265-1267.

https://www.thieme-connect.com/ejournals/html/synlett/doi/10.1055/s-0030-1260541

SYNLETT Cluster: Brønsted Acid Catalysis

21.

Precise Control of Spontaneous Molecular Assembly of Chiral Tetraaminophosphonium Aryloxide-Arylhydroxide(s) in Solution

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

Angew. Chem. Int. Ed. 2011, 50, 3681-3683.

DOI: 10.1002/anie.201007752

Selected as "Hot Paper"

20.

Chiral 1,2,3-Triazoliums as New Cationic Organic Catalysts with Anion-Recognition Ability: Application to Asymmetric Alkylation of Oxindoles

Ohmatsu, Kohsuke, Kiyokawa, Mari, Ooi, Takashi

J. Am. Chem. Soc. 2011, 133, 1307-1309.

DOI: 10.1021/ja1102844

Highlighted in Synfacts 2011, 324. http://dx.doi.org/10.1055/s-0030-1259452

19.

Catalytic Asymmetric Protonation of α-Amino Acid-Derived Ketene Disilyl Acetals Using P-Spiro Diaminodioxaphosphonium Barfates as Chiral Proton

Uraguchi, Daisuke; Kinoshita, Natsuko; Ooi, Takashi

J. Am. Chem. Soc. 2010, 132, 12240-12242.

DOI: 10.1021/ja105945z

Highlighted in Synfacts 2010, 1300. http://dx.doi.org/10.1055/s-0030-1258790

18.

Catalytic Asymmetric Direct Henry Reaction of Ynals: Short Syntheses of (2S,3R)-(+)-Xestoaminol C and (-)-Codonopsinines

Uraguchi, Daisuke; Nakamura, Shinji; Ooi, Takashi

Angew. Chem. Int. Ed. 2010, 49, 7562-7565.

DOI: 10.1002/anie.201004072

Highlighted in Synfacts 2010, 1309. http://dx.doi.org/10.1055/s-0030-1258782

17.

Chiral Ammonium Betaines as an Ionic Nucleophilic Catalyst

Uraguchi, Daisuke; Koshimoto, Kyohei; Miyake, Shuhei; Ooi, Takashi

Angew. Chem. Int. Ed. 2010, 49, 5567-5569.

DOI: 10.1002/anie.201002315

Highlighted in Synfacts 2010, 1075. http://dx.doi.org/10.1055/s-0030-1257971

16.

Catalytic Asymmetric Hydrophosphonylation of Ynones

Uraguchi, Daisuke; Ito, Takaki; Nakamura, Shinji; Ooi, Takashi

Chem. Sci. 2010, 1, 488-490.

DOI: 10.1039/c0sc00268b

Highlighted in Synfacts 2011, 50. http://dx.doi.org/10.1055/s-0030-1259171

15.

Performance of C1-symmetric chiral ammonium betaines as a catalyst for the enantioselective Mannich-type reaction of α-nitrocarboxylates

Uraguchi, Daisuke; Koshimoto, Kyohei; Sanada, Chisato; Ooi, Takashi

Tetrahedron: Asymmetry. 2010, 21, 1189-1190.

http://dx.doi.org/10.1016/j.tetasy.2010.04.006

14.

Flexible Synthesis, Structural Determination, and Synthetic Application of a New C1-Symmetric Chiral Ammonium Betaine

Uraguchi, Daisuke; Koshimoto, Kyohei; Ooi, Takashi

Chem. Commun. 2010, 46, 300-302.

http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b916627k

Selected as "Hot Article"

Highlighted in Synfacts 2010, 0232. http://dx.doi.org/10.1055/s-0029-1219139

13.

Diastereo- and Enantioselective Direct Henry Reaction of Pyruvates Mediated by Chiral P-Spiro Tetraaminophosphonium salts

Uraguchi, Daisuke; Ito, Takaki; Nakamura, Shinji; Sakaki, Sawako; Ooi, Takashi

Chem. Lett. 2009, 38, 1052.

http://www.jstage.jst.go.jp/article/cl/38/11/38_1052/_article

12.

Chiral Organic Ion Pair Catalysts Assembled Through a Hydrogen-Bonding Network

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

Science. 2009, 326, 120-123.

http://www.sciencemag.org/cgi/content/abstract/326/5949/120

Highlighted in C & EN 2009, 87, 25-26. [Science & Technology Concentrates (August 31)]

プレスリリース (名古屋大学HP)

読売新聞、日刊工業新聞 (8月28日朝刊)掲載

Highlighted in Synfacts 2009, 1408. http://dx.doi.org/10.1055/s-0029-1218214

Highlighted in ACIE DOI: 10.1002/anie.200906392

11.

Al Lewis acid-catalyzed regiodivergent 1,2-rearrangement of α-siloxy aldehydes: scope and mechanism

Ohmatsu, Kohsuke; Tanaka, Takayuki; Ooi, Takashi; Maruoka, Keiji

Tetrahedron 2009, 65, 7516-7522.

http://dx.doi.org/10.1016/j.tet.2009.06.126

10.

Chiral Arylaminophosphonium Barfates as a New Class of Charged Brønsted Acid for the Enantioselective Activation of Nonionic Lewis Bases

Uraguchi, Daisuke; Nakashima, Daisuke; Ooi, Takashi

J. Am. Chem. Soc. 2009, 131, 7242-7243.

http://pubs.acs.org/doi/abs/10.1021/ja903271t
Highlighted in Synfacts 2009, 562. http://dx.doi.org/10.1055/s-0029-1217582

9.

Generation of Chiral Phosphonium Dialkyl Phosphite as a Highly Reactive P-Nucleophile: Application to Asymmetric Hydrophosphonylation of Aldehydes

Uraguchi, Daisuke; Ito, Takaki; Ooi, Takashi

J. Am. Chem. Soc. 2009, 131, 3836-3837.

http://pubs.acs.org/doi/abs/10.1021/ja810043d

Correction

J. Am. Chem. Soc. 2017, 139,3299?3299.

http://pubs.acs.org/doi/abs/10.1021/jacs.7b01263

Highlighted in Synfacts 2009, 562. http://dx.doi.org/10.1055/s-0029-1216583

Highlighted in Synfacts 2009, 645. http://dx.doi.org/10.1055/s-0029-1216717

8.

Asymmetric Synthesis of α,α-Disubstituted-α-Amino Acids via Enantioselective Alkylation of Azlactones under Biphasic Conditions Using P-Spiro Chiral Tetraaminophosphonium Salts as a Phase-Transfer Catalyst

Uraguchi, Daisuke; Asai, Yoshihiro; Seto, Yuki; Ooi, Takashi

Synlett 2009, 658-660.

http://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-0028-1087812

SYNLETT Cluster: Phase Transfer Catalyst for Asymmetric Synthesis

7.

Site-directed Asymmetric Quaternization of a Peptide Backbone at a C-Terminal Azlactone

Uraguchi, Daisuke; Asai, Yoshihiro; Ooi, Takashi

Angew. Chem. Int. Ed. 2009, 48, 733-737.

http://www.thieme-connect.com/ejournals/abstract/synlett/doi/10.1055/s-0028-1087812

Selected as a "inside cover picture"

Highlighted in Synfacts 2009, 205. http://dx.doi.org/10.1055/s-0028-1087586

6.

Chiral Tetraaminophosphonium Carboxylate-Catalyzed Direct Mannich-Type Reaction

Uraguchi, Daisuke; Ueki, Yusuke; Ooi, Takashi

J. Am. Chem. Soc. 2008, 130, 14088-14089.

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/asap/abs/ja806311e.html

Highlighted in Synfacts 2008, 1327. http://dx.doi.org/10.1055/s-0028-1083579

5.

Chiral Ammonium Betaines: A Bifunctional Organic Base Catalyst for Asymmetric Mannich-type Reaction of α-Nitrocarboxylates

Uraguchi, Daisuke; Koshimoto, Kyohei; Ooi, Takashi

J. Am. Chem. Soc. 2008, 130, 10878-10879.

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/asap/abs/ja8041004.html

Highlighted in Synfacts 2008, 1105. http://dx.doi.org/10.1055/s-2008-1078149 (Synfact of the month)

4.

Synthesis of Chiral Tetraaminophosphonium Chlorides from N-BOC α-Amino Acid Esters

Uraguchi, Daisuke; Sakaki, Sawako; Ueki, Yusuke; Ito, Takaki; Ooi, Takashi

Heterocycles 2008, 76, 1081-1085.

http://www.heterocycles.jp/library/abstract.php?article=3158

3.

Chiral Tetraaminophosphonium Salt-Mediated Asymmetric Direct Henry Reaction

Uraguchi, Daisuke; Sakaki, Sawako; Ooi, Takashi

J. Am. Chem. Soc. 2007, 129, 12392-12393.

http://pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2007/129/i41/abs/ja075152+.html

Highlighted in Synfacts 2007, 1309. http://dx.doi.org/10.1055/s-2007-991331 (Synfact of the month)

Highlighted in Synform 2007, A7-A8. http://dx.doi.org/10.1055/s-2007-1000843 (Synstory)

2.

Advantage of in situ generation of N-arylsulfonyl imines from α-amide sulfones in the phase-transfer-catalyzed asymmetric Strecker reaction

Ooi, Takashi; Uematsu, Yukitaka; Fujimoto, Jun; Fukumoto, Kazuhiro; Maruoka, Keiji

Tetrahedron Letters 2007, 48, 1337-1340.

http://dx.doi.org/10.1016/j.tetlet.2006.12.122

1.

Asymmetric Strecker Reaction of Aldimines Using Aqueous Potassium Cyanide by Phase-Transfer Catalysis of Chiral Quaternary Ammonium Salts with a Tetranaphthyl Backbone.

Ooi, Takashi; Uematsu, Yukitaka; Maruoka, Keiji

J. Am. Chem. Soc 2006, 128, 2548-2549.

http://dx.doi.org/10.1021/ja058066n

ページの先頭へ

総説等 : Reviews

8.

Design of supramolecular chiral ligands for asymmetric metal catalysis

Kohsuke Ohmatsu, Takashi Ooi

Tetrahedron Letters 2015, 56, 2043-2048.

http://dx.doi.org/10.1016/j.tetlet.2015.02.096

7.

Development of Ion-Paired Chiral Ligands for Asymmetric Transition-Metal Catalysis

大松 亨介, 大井 貴史

有機合成化学協会誌 2015, 73, 140-150.

http://doi.org/10.5059/yukigoseikyokaishi.73.140

6.

Development of P-Spiro Chiral Aminophosphonium Salts as a New Class of Versatile Organic Molecular Catalyst

浦口 大輔, 大井 貴史

有機合成化学協会誌 2010, 68, 1185-1194.

http://www.jstage.jst.go.jp/article/yukigoseikyokaishi/68/11/1185/_pdf/-char/ja/

5.

「水素結合供与型キラルホスホニウム/有機アニオンが示す新たなイオン「対」触媒作用」

上木 佑介, 浦口 大輔, 大井 貴史

触媒 2010, 52, 509-514.

http://www.shokubai.org/jnl/tmpPdf/1295275473a.pdf

4.

P-スピロ型テトラアミノホスホニウム塩の創製と有機分子触媒としての機能発現」

浦口 大輔

触媒 2008, 50, 683-687.

PermaLink

3.

Development and Applications of C2-Symmetric, Chiral, Phase-Transfer Catalysts

Ooi, Takashi; Maruoka, Keiji

Aldrichimia Acta 2007, 40, 77-86.

http://www.sigmaaldrich.com/aldrich/acta/al_acta_40_03.pdf

2.

Design of Chiral Organocatalysts for Practical Asymmetric Synthesis of Amino Acid Derivatives

Maruoka, Keiji; Ooi, Takashi; Kano, Taichi

Chem. Commun. 2007, 1487-1495.

DOI: 10.1039/b613049f

1.

Recent Advances in Asymmetric Phase-Transfer Catalysis

Ooi, Takashi; Maruoka, Keiji

Chem. Commun. 2007, 46, 4222-4266.

DOI: 10.1002/anie.200601737

ページの先頭へ

解説・紀要等

7.

α-アミノカルボニル化合物の効率的不斉合成

中島 翼,大松 亨介, 大井 貴史

PHARMSTAGE 2017, 17, 61-67.

6.

「[5.5]-P-スピロ型キラルテトラアミノホスホニウム塩を用いる触媒的分子変換」

浦口 大輔, 大井 貴史

Wako Organic Square 2017, 59(3), 2-5.

http://www.wako-chem.co.jp/siyaku/journal/org/pdf/org59.pdf

5.

「Lectureship Award MBLA 2014受賞講演ツアーを終えて」

浦口 大輔

有機合成化学協会誌 2015, 73, 653-662.

http://doi.org/10.5059/yukigoseikyokaishi.73.653

4.

「忘れられた反応剤Davis’オキサジリジン」

浦口 大輔, 堤 亮祐, 大井 貴史

月刊「化学」 2013, 68, 66-67.

3.

「D2対称型光学活性テトラアミノホスホニウム塩の創製と相間移動触媒反応への応用」

浦口 大輔, 大井 貴史

月刊ファインケミカル 2010, 39, 42-48.

2.

「光学活性な炭素の三角形を作る―Corey-Chaykovsky反応と親電子剤活性化法の組み合わせ」

浦口 大輔, 大井 貴史

化学 2008, 63, 66-67.

1.

「二相系でのイミンの系内発生を活かした触媒的不斉合成」

大井 貴史

Organometallic News 2008, 40-43

ページの先頭へ

著書等 : Books

12.

「イオン対を中心とした不斉塩基触媒」

浦口 大輔, 大井 貴史
CSJカレントレビュー「有機分子触媒の化学」” 日本化学会; 109-117 (2016)

11.

“Site-Selective Conjugate Addition through Catalytic Generation of Ion-Pairing Intermediates”

Daisuke Uraguchi, Takashi Ooi
Topics in Current Chemistry: Site Selective Catalysis” T. Kawabata Ed. Springer; 55-84 (2016)

10.

「イオン性キラル触媒〜新しい分子設計へのこだわり〜」

大松 亨介, 大井 貴史
CSJカレントレビュー「キラル化学:その起源から最新のキラル材料研究まで」” 八島 栄治 日本化学会; (2013)

9.

“Axially Chiral C2-Symmetric Catalysts”
Daisuke Uraguchi, Kohsuke Ohmatsu, Takashi Ooi
Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications” P. I. Dalko Eds. Wiley-VCH; 161-193 (2013)

8.

“Asymmetric phase-transfer catalysis”
Kohsuke Ohmatsu, Daisuke Uraguchi, Takashi Ooi
Stereoselective Synthesis of Drugs and Natural Products” V. Andrushko, N. Andrushko Eds. Wiley-VCH; 119-144 (2013)

7.

"6.1 C-C Bond Formation: Alkylation"

Uraguchi, Daisuke; Ooi, Takashi

"COMPREHENSIVE CHIRALITY" Elsevier Science; 1-36 (2012)

6.

"Hydrogen-Bonding Catalysts Other than Ureas and Thioureas"

Uraguchi, Daisuke; Ooi, Takashi

"Science of Synthesis: Asymmetric Organicatalysis 2" Thieme; 413-435 (2012)

5.

"Development of phase-transfer-catalyzed asymmetric Strecker reaction based on the molecular design of chiral quaternary ammonium salts"

Ooi, Takashi

"ACS Symposium Series (2009), 1009(Asymmetric Synthesis and Application of .alpha.-Amino Acids)" ACS Publications; 177-189 (2009)

4.

“Chiral quaternary ammonium fluorides for asymmetric synthesis”
Shirakawa, Seiji; Ooi, Takashi; Maruoka, Keiji
Asymmetric Phase Transfer Catalysis” K. Maruoka Eds. Wiley-VCH; 189-206 (2008)

3.

“Cinchona-derived chiral phase-transfer catalysts for amino acid synthesis”
T. Ooi
Asymmetric Phase Transfer Catalysis” K. Maruoka Eds. Wiley-VCH; 9-33 (2008)

2.

“Chiral Carbonyl Lewis Acid Complexes in Asymmetric Syntheses”
K. Maruoka, T. Ooi
Asymmetric Synthesis - The Essentials” M. Christmann, S. Bräse Eds. VCH; 121-125 (2007)

1.

“Ammonium Ions as Chiral Templates”
T. Ooi, K. Maruoka
Enantioselective Organocatalysis: Reactions and Experimental Procedures” P. I. Dalko Ed. Wiley; 121-150 (2007)

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